Bis[2-(diphenylphosphanyl-κP)benzaldehyde]iodidogold(I)
نویسندگان
چکیده
In the title compound, [AuI(C(19)H(15)OP)(2)], the complete mol-ecule is generated by the application of twofold symmetry. The Au(I) atom is in a trigonal-planar geometry within an IP(2) donor set with the greatest distortion seen in the P-Au-P angle [128.49 (3) °]. Close intra-molecular Au⋯O inter-actions [3.172 (3) Å] are observed. No specific inter-molecular inter-actions are noted in the crystal packing.
منابع مشابه
{1,3-Bis[(diphenylphosphanyl-κP)oxy]propane}dicarbonyliron(0)
The structure of the title compound, [Fe(C(27)H(26)O(2)P(2))(CO)(2)], exhibits a distorted tetra-hedral coordination [bond angle range = 96.31 (12)-119.37 (4)°], comprising two P-atom donors from the chelating 1,3-bis-[(diphenyl-phosphan-yl)-oxy]propane ligand [Fe-P = 2.1414 (10) and 2.1462 (10) Å] and two carbonyl ligands [Fe-C = 1.763 (4) and 1.765 (3) Å].
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